Abstract
GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS,
VOL. 3,
1019,
13 PP., 2002
doi:10.1029/2001GC000264 [Citation]
Evidence for preindustrial variations in the marine surface water carbonate system from coralline sponges
GEOMAR, Forschungszentrum für Marine Geowissenschaften, Wischhofstr. 1-3, Kiel, D-24148 Germany
GEOMAR, Forschungszentrum für Marine Geowissenschaften, Wischhofstr. 1-3, Kiel, D-24148 Germany
GEOMAR, Forschungszentrum für Marine Geowissenschaften, Wischhofstr. 1-3, Kiel, D-24148 Germany
GEOMAR, Forschungszentrum für Marine Geowissenschaften, Wischhofstr. 1-3, Kiel, D-24148 Germany
Institut für Geologie, Universität Erlangen, Schlossgarten 5, Erlangen, D-91054 Germany
Thetis-Institut für biomolekulare Naturstoffforschung, Notkestr. 85, Hamburg, D-22607 Germany
Geobiologie - Geowissenschaftliches Zentrum Göttingen GZG, Goldschmidtstr. 3, Göttingen, D-37077 Germany
Coralline sponge skeletons are excellent tools for reconstructing the carbon isotope history of dissolved inorganic carbon (DIC) in tropical surface waters. Carbon isotope records from coralline sponges clearly reflect the industrial 12C increase in atmospheric CO2 with a precision that permits quantitative interpretations. We find from a set of δ13C records of four Caribbean sponge specimens that the isotopic response of surface water DIC to the changing isotopic composition of atmospheric CO2 varied dynamically during the last century, depending on the rate of atmospheric change. Three of our sponges provide 600 year long δ13C records. For the first time, we can reconstruct surface water δ13CDIC for the full history of the industrial CO2 release as well as the preceding preindustrial period back to the beginning of the Little Ice Age. This provides a well-founded estimate of the anthropogenically uninfluenced, preindustrial background level of surface water 13C/12C ratios. Our records show small but systematic variations that appear to be linked to the climate fluctuations of the Little Ice Age.
Received 28 October 2001; accepted 30 January 2002; published 21 March 2002.
Citation: (2002), Evidence for preindustrial variations in the marine surface water carbonate system from coralline sponges, Geochem. Geophys. Geosyst., 3(3), 1019, doi:10.1029/2001GC000264.
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