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AGU: Geophysical Research Letters

 

Index Terms

  • Atmospheric Composition and Structure: Air/sea constituent fluxes
  • Oceanography: Biological and Chemical: Carbon cycling
  • Global Change: Biogeochemical processes
  • Oceanography: General: Climate and interannual variability
  • Oceanography: General: Numerical modeling

Abstract

Interannual variability of air-sea O2 fluxes and the determination of CO2 sinks using atmospheric O2/N2

Galen A. McKinley

Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

Michael J. Follows

Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

John Marshall

Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

Song-Miao Fan

Atmospheric and Ocean Sciences Program, Princeton University, Princeton, New Jersey, USA

Motivated by the use of atmospheric O2/N2 to determine CO2 sinks under the assumption of negligible interannual variability in air-sea O2 fluxes, we examine interannual fluctuations of the global air-sea flux of O2 during the period 1980–1998 using a global ocean circulation and biogeochemistry model along with an atmospheric transport model. It is found that both the El Niño/Southern Oscillation (ENSO) cycle and wintertime convection in the North Atlantic are primary drivers of global air-sea oxygen flux interannual variability. Model estimated extremes of O2 flux variability are −70/+100 × 1012 mol/yr (Tmol/yr), where positive fluxes are to the atmosphere. O2/N2 variability could cause an up to ±1.0 PgC/yr error in estimates of interannual variability in land and ocean CO2 sinks derived from atmospheric O2/N2 observations.

Published 1 February 2003.

Citation: McKinley, G. A., M. J. Follows, J. Marshall, and S.-M. Fan (2003), Interannual variability of air-sea O2 fluxes and the determination of CO2 sinks using atmospheric O2/N2, Geophys. Res. Lett., 30(3), 1101, doi:10.1029/2002GL016044.

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