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AGU: Journal of Geophysical Research, Atmospheres

 

Index Terms

  • Atmospheric Composition and Structure: Pollution—urban and regional
  • Atmospheric Composition and Structure: Troposphere—composition and chemistry
  • Atmospheric Composition and Structure: Troposphere—constituent transport and chemistry
  • Global Change: Atmosphere
Abstract
Cited By (Apache Tomcat/4.1.31 - Error report

HTTP Status 500 -


type Exception report

message

description The server encountered an internal error () that prevented it from fulfilling this request.

exception

javax.servlet.ServletException: Servlet execution threw an exception
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:222)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:146)
	at org.apache.catalina.core.StandardWrapperValve.invoke(StandardWrapperValve.java:209)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardContextValve.invoke(StandardContextValve.java:144)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardContext.invoke(StandardContext.java:2358)
	at org.apache.catalina.core.StandardHostValve.invoke(StandardHostValve.java:133)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.valves.ErrorDispatcherValve.invoke(ErrorDispatcherValve.java:118)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:594)
	at org.apache.catalina.valves.ErrorReportValve.invoke(ErrorReportValve.java:116)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:594)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardEngineValve.invoke(StandardEngineValve.java:127)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.coyote.tomcat4.CoyoteAdapter.service(CoyoteAdapter.java:152)
	at org.apache.jk.server.JkCoyoteHandler.invoke(JkCoyoteHandler.java:300)
	at org.apache.jk.common.HandlerRequest.invoke(HandlerRequest.java:374)
	at org.apache.jk.common.ChannelSocket.invoke(ChannelSocket.java:743)
	at org.apache.jk.common.ChannelSocket.processConnection(ChannelSocket.java:675)
	at org.apache.jk.common.SocketConnection.runIt(ChannelSocket.java:866)
	at org.apache.tomcat.util.threads.ThreadPool$ControlRunnable.run(ThreadPool.java:683)
	at java.lang.Thread.run(Thread.java:595)

root cause

java.lang.OutOfMemoryError: unable to create new native thread
	at java.lang.Thread.start0(Native Method)
	at java.lang.Thread.start(Thread.java:574)
	at oracle.jdbc.pool.OracleConnectionCacheManager.checkAndStartThread(OracleConnectionCacheManager.java:823)
	at oracle.jdbc.pool.OracleImplicitConnectionCache.setConnectionCacheProperties(OracleImplicitConnectionCache.java:1918)
	at oracle.jdbc.pool.OracleImplicitConnectionCache.<init>(OracleImplicitConnectionCache.java:174)
	at oracle.jdbc.pool.OracleConnectionCacheManager.createCache(OracleConnectionCacheManager.java:265)
	at org.agu.oracle.jdbc.ConnCacheBean.initializeConnectionCache(ConnCacheBean.java:272)
	at org.agu.oracle.jdbc.ConnCacheBean.<init>(ConnCacheBean.java:81)
	at org.agu.oracle.jdbc.ConnCacheBean.getInstance(ConnCacheBean.java:94)
	at org.agu.oracle.jdbc.ForwardLinkingUtil.doGet(ForwardLinkingUtil.java:79)
	at javax.servlet.http.HttpServlet.service(HttpServlet.java:696)
	at javax.servlet.http.HttpServlet.service(HttpServlet.java:809)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:200)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:146)
	at org.apache.catalina.core.StandardWrapperValve.invoke(StandardWrapperValve.java:209)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardContextValve.invoke(StandardContextValve.java:144)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardContext.invoke(StandardContext.java:2358)
	at org.apache.catalina.core.StandardHostValve.invoke(StandardHostValve.java:133)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.valves.ErrorDispatcherValve.invoke(ErrorDispatcherValve.java:118)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:594)
	at org.apache.catalina.valves.ErrorReportValve.invoke(ErrorReportValve.java:116)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:594)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.catalina.core.StandardEngineValve.invoke(StandardEngineValve.java:127)
	at org.apache.catalina.core.StandardPipeline$StandardPipelineValveContext.invokeNext(StandardPipeline.java:596)
	at org.apache.catalina.core.StandardPipeline.invoke(StandardPipeline.java:433)
	at org.apache.catalina.core.ContainerBase.invoke(ContainerBase.java:948)
	at org.apache.coyote.tomcat4.CoyoteAdapter.service(CoyoteAdapter.java:152)
	at org.apache.jk.server.JkCoyoteHandler.invoke(JkCoyoteHandler.java:300)
	at org.apache.jk.common.HandlerRequest.invoke(HandlerRequest.java:374)
	at org.apache.jk.common.ChannelSocket.invoke(ChannelSocket.java:743)
	at org.apache.jk.common.ChannelSocket.processConnection(ChannelSocket.java:675)
	at org.apache.jk.common.SocketConnection.runIt(ChannelSocket.java:866)
	at org.apache.tomcat.util.threads.ThreadPool$ControlRunnable.run(ThreadPool.java:683)
	at java.lang.Thread.run(Thread.java:595)


Apache Tomcat/4.1.31

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Abstract

Rapid growth of hydrofluorocarbon 134a and hydrochlorofluorocarbons 141b, 142b, and 22 from Advanced Global Atmospheric Gases Experiment (AGAGE) observations at Cape Grim, Tasmania, and Mace Head, Ireland

S. O'Doherty

School of Chemistry, University of Bristol, Bristol, UK

D. M. Cunnold

School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA

A. Manning

Climate Research, UK Met Office, Bracknell, UK

B. R. Miller

Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California, USA

R. H. J. Wang

School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA

P. B. Krummel

Atmospheric Research, Commonwealth Scientific and Industrial Research Organisation, Aspendale, Victoria, Australia

P. J. Fraser

Atmospheric Research, Commonwealth Scientific and Industrial Research Organisation, Aspendale, Victoria, Australia

P. G. Simmonds

School of Chemistry, University of Bristol, Bristol, UK

A. McCulloch

School of Chemistry, University of Bristol, Bristol, UK

R. F. Weiss

Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California, USA

P. Salameh

Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California, USA

L. W. Porter

Cape Grim Baseline Air Pollution Station, Bureau of Meteorology, Smithton, Tasmania, Australia

R. G. Prinn

Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

J. Huang

Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

G. Sturrock

Climate Research, UK Met Office, Bracknell, UK

D. Ryall

Climate Research, UK Met Office, Bracknell, UK

R. G. Derwent

Climate Research, UK Met Office, Bracknell, UK

S. A. Montzka

Climate Monitoring and Diagnostics Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado, USA

An update of in situ Advanced Global Atmospheric Gases Experiment (AGAGE) hydrofluorocarbon (HFC)/hydrochlorofluorocarbon (HCFC) measurements made at Mace Head, Ireland, and Cape Grim, Tasmania, from 1998 to 2002 are reported. HCFC-142b, HCFC-141b, HCFC-22 and HFC-134a show continued rapid growth in the atmosphere at mean rates of 1.1, 1.6, 6.0, and 3.4 ppt/year, respectively. Emissions inferred from measurements are compared to recent estimates from consumption data. Minor updates to the industry estimates of emissions are reported together with a discussion of how to best determine OH concentrations from these trace gas measurements. In addition, AGAGE measurements and derived emissions are compared to those deduced from NOAA-Climate Monitoring and Diagnostics Laboratory flask measurements (which are mostly made at different locations). European emission estimates obtained from Mace Head pollution events using the Nuclear Accident Model (NAME) dispersion model and the best fit algorithm (known as simulated annealing) are presented as 3-year rolling average emissions over Europe for the period 1999–2001. Finally, the measurements of HCFC-141b, HCFC-142b, and HCFC-22 discussed in this paper have been combined with the Atmospheric Lifetime Experiment (ALE)/Global Atmospheric Gases Experiment (GAGE)/AGAGE measurements of CFC-11, CFC-12, CFC-113, CCl4, and CH3CCl3 to produce the evolution of tropospheric chlorine loading.

Received 23 October 2003; accepted 3 February 2004; published 26 March 2004.

Citation: O'Doherty, S., et al. (2004), Rapid growth of hydrofluorocarbon 134a and hydrochlorofluorocarbons 141b, 142b, and 22 from Advanced Global Atmospheric Gases Experiment (AGAGE) observations at Cape Grim, Tasmania, and Mace Head, Ireland, J. Geophys. Res., 109, D06310, doi:10.1029/2003JD004277.

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