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GEOPHYSICAL RESEARCH LETTERS, VOL. 31, L21506, doi:10.1029/2004GL020908, 2004

Tracing sources of nitrate in snowmelt runoff using a high-resolution isotopic technique

N. Ohte

Graduate School of Agriculture, Kyoto University, Kyoto, Japan


S. D. Sebestyen

College of Environmental Science and Forestry, State University of New York, Syracuse, New York, USA


J. B. Shanley

U.S. Geological Survey, Montpelier, Vermont, USA


D. H. Doctor

U.S. Geological Survey, Menlo Park, California, USA


C. Kendall

U.S. Geological Survey, Menlo Park, California, USA


S. D. Wankel

U.S. Geological Survey, Menlo Park, California, USA


E. W. Boyer

Department of Environmental Science, Policy and Management, University of California, Berkeley, California, USA


Abstract

The denitrifier method to determine the dual isotopic composition (δ15N and δ18O) of nitrate is well suited for studies of nitrogen contributions to streams during runoff events. This method requires only 70 nmol of NO3 − and enables high throughput of samples. We studied nitrate sources to a headwater stream during snowmelt by generating a high-temporal resolution dataset at the Sleepers River Research Watershed in Vermont, USA. In the earliest phase of runoff, stream NO3 − concentrations were highest and stream discharge, NO3 − concentrations, and δ18O of NO3 − generally tracked one another during diurnal melting. The isotopic composition of stream NO3 − varied in-between atmospheric and groundwater NO3 − end members indicating a direct contribution of atmospherically-derived NO3 − from the snow pack to the stream. During the middle to late phases of snowmelt, the source shifted toward soil NO3 − entering the stream via shallow subsurface flow paths.

Received 3 July 2004; accepted 11 October 2004; published 6 November 2004.

Index Terms: 1615 Global Change: Biogeochemical processes (4805); 1719 History of Geophysics: Hydrology; 1860 Hydrology: Runoff and streamflow; 4870 Oceanography: Biological and Chemical: Stable isotopes.

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Citation: Ohte, N., S. D. Sebestyen, J. B. Shanley, D. H. Doctor, C. Kendall, S. D. Wankel, and E. W. Boyer (2004), Tracing sources of nitrate in snowmelt runoff using a high-resolution isotopic technique, Geophys. Res. Lett., 31, L21506, doi:10.1029/2004GL020908.