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GEOPHYSICAL RESEARCH LETTERS,
VOL. 32,
L11305,
doi:10.1029/2005GL022792,
2005
Nitrogen isotopes of the mantle: Insights from mineral separates
Tobias P. Fischer
Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
Naoto Takahata
Ocean Research Institute, University of Tokyo, Tokyo, Japan
Yuji Sano
Ocean Research Institute, University of Tokyo, Tokyo, Japan
Hirochika Sumino
Laboratory for Earthquake Chemistry, University of Tokyo, Tokyo, Japan
David R. Hilton
Fluids and Volatiles Laboratory, Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California,
USA
Abstract
We present the first nitrogen (N) isotope measurements determined by in-vacuo crushing of mineral separates from arc lavas,
OIBs (Ocean Island Basalts), and mantle xenoliths. Measured OIB δ15N values range from ∼−8‰ for the northern rift zone in Iceland to +3.1‰ for a dunite nodule from Hawaii. Most arc-related
olivines show distinctly positive values - up to +6.2‰ (Cerro Negro, Nicaragua). The measured N isotope values in olivine
separates are similar to gas samples collected at the same localities, suggesting that both media (olivines and gases) sample
volatiles primarily derived from the magma. This observation also implies that N isotope fractionation does not occur during
magma degassing, a notion supported by 4He/40Ar* data. Our results indicate a heterogeneous mantle source region, in terms of N isotopic composition, that may have resulted
from surface recycling of N at some localities.
Received 22
February
2005;
accepted 5
May
2005;
published 10
June
2005.
Index Terms: 1025 Geochemistry: Composition of the mantle; 1036 Geochemistry: Magma chamber processes (3618); 1031 Geochemistry: Subduction zone processes (3060, 3613, 8170, 8413); 1041 Geochemistry: Stable isotope geochemistry (0454, 4870); 1042 Geochemistry: Mineral and crystal chemistry (3620).
Read Full Article (file size: 186711 bytes) Cited by
Citation: Fischer, T. P., N. Takahata, Y. Sano, H. Sumino, and D. R. Hilton
(2005),
Nitrogen isotopes of the mantle: Insights from mineral separates,
Geophys. Res. Lett.,
32,
L11305,
doi:10.1029/2005GL022792.
Copyright 2005 by the American Geophysical Union.
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