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AGU: Journal of Geophysical Research, Atmospheres

 

Keywords

  • biomass burning
  • aerosol morphology and size
  • fractal properties

Index Terms

  • Atmospheric Composition and Structure: Aerosols and particles
  • Atmospheric Composition and Structure: Pollution: urban and regional
  • Biogeosciences: Pollution: urban, regional and global
Abstract
Cited By (11)
 

Abstract

Emissions from the laboratory combustion of wildland fuels: Particle morphology and size

Rajan K. Chakrabarty

Desert Research Institute, Nevada System of Higher Education, Reno, Nevada, USA

Hans Moosmüller

Desert Research Institute, Nevada System of Higher Education, Reno, Nevada, USA

Mark A. Garro

Desert Research Institute, Nevada System of Higher Education, Reno, Nevada, USA

W. Patrick Arnott

Desert Research Institute, Nevada System of Higher Education, Reno, Nevada, USA

John Walker

Desert Research Institute, Nevada System of Higher Education, Reno, Nevada, USA

Ronald A. Susott

Retired from USDA Forest Service, Rocky Mountain Research Station, Fire Sciences Laboratory, Missoula, Montana, USA

Ronald E. Babbitt

Retired from USDA Forest Service, Rocky Mountain Research Station, Fire Sciences Laboratory, Missoula, Montana, USA

Cyle E. Wold

USDA Forest Service, Rocky Mountain Research Station, Fire Sciences Laboratory, Missoula, Montana, USA

Emily N. Lincoln

USDA Forest Service, Rocky Mountain Research Station, Fire Sciences Laboratory, Missoula, Montana, USA

Wei Min Hao

USDA Forest Service, Rocky Mountain Research Station, Fire Sciences Laboratory, Missoula, Montana, USA

The morphology of particles emitted by wildland fires contributes to their physical and chemical properties but is rarely determined. As part of a study at the USFS Fire Sciences Laboratory (FSL) investigating properties of particulate matter emitted by fires, we studied the size, morphology, and microstructure of particles emitted from the combustion of eight different wildland fuels (i.e., sagebrush, poplar wood, ponderosa pine wood, ponderosa pine needles, white pine needles, tundra cores, and two grasses) by scanning electron microscopy. Six of these fuels were dry, while two fuels, namely the tundra cores and one of the grasses, had high fuel moisture content. The particle images were analyzed for their density and textural fractal dimensions, their monomer and agglomerate number size distributions, and three different shape descriptors, namely aspect ratio, root form factor, and roundness. The particles were also probed with energy dispersive X-ray spectroscopy confirming their carbonaceous nature. The density fractal dimension of the agglomerates was determined using two different techniques, one taking into account the three-dimensional nature of the particles, yielding values between 1.67 and 1.83, the other taking into account only the two-dimensional orientation, yielding values between 1.68 and 1.74. The textural fractal dimension that describes the roughness of the boundary of the two-dimensional projection of the particle was between 1.10 and 1.19. The maximum length of agglomerates was proportional to a power a of their diameter and the proportionality constant and the three shape descriptors were parameterized as function of the exponent a.

Received 9 September 2005; accepted 6 January 2006; published 5 April 2006.

Citation: Chakrabarty, R. K., H. Moosmüller, M. A. Garro, W. P. Arnott, J. Walker, R. A. Susott, R. E. Babbitt, C. E. Wold, E. N. Lincoln, and W. M. Hao (2006), Emissions from the laboratory combustion of wildland fuels: Particle morphology and size, J. Geophys. Res., 111, D07204, doi:10.1029/2005JD006659.

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