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AGU: Water Resources Research

 

Keywords

  • Borden
  • chlorinated solvents
  • contaminant transport
  • heterogeneity
  • hydrophobic organic contaminants
  • nonideal transport

Index Terms

  • Biogeosciences: Contaminant and organic biogeochemistry
  • Hydrology: Anthropogenic effects
  • Hydrology: Groundwater quality
  • Hydrology: Groundwater transport

Abstract

WATER RESOURCES RESEARCH, VOL. 42, W01413, 13 PP., 2006
doi:10.1029/2005WR003977

Spatial distributions of perchloroethylene reactive transport parameters in the Borden Aquifer

Richelle M. Allen-King

Department of Geology, State University of New York at Buffalo, Buffalo, New York, USA

Dana Packard Divine

Kleinfelder, Bellevue, Washington, USA

Michel J. L. Robin

Department of Earth Sciences, University of Ottawa, Ottawa, Ontario, Canada

J. Richard Alldredge

Department of Statistics, Washington State University, Pullman, Washington, USA

David R. Gaylord

Department of Geology, Washington State University, Pullman, Washington, USA

We determined the descriptive statistical and spatial geostatistical properties of the perchloroethene ln K d and the ln k of a 1.5 m thick by 10 m horizontal transect of the Borden aquifer near the location of the Stanford-Waterloo (SW) tracer experiment. The ln K d distribution is not normal and is right skewed because of a few high values that occur localized in two regions of the transect. In contrast, the ln k data can be characterized by a normal distribution. A linear regression of ln K d on ln k yields a statistically significant positive correlation, also shown at small lags in the cross correlogram. No significant vertical or horizontal trend in the ln K d data was detected. The semivariogram ranges of ln k and ln K d differ from one another in the vertical direction (0.33 ± 0.06 m and 0.20 ± 0.04 m, respectively) and are much less than the horizontal ranges (a few meters). Despite significant effort the horizontal range of ln K d remains poorly characterized because of limitations of the sample locations. Many of the characteristics described above do not match those assumed in prior theoretical studies that examined the importance of various aquifer characteristics on SW tracer transport. We suggest that there is knowledge to be gained by revisiting the conclusions of these prior studies in light of the new information presented here.

Received 20 January 2005; accepted 4 October 2005; published 24 January 2006.

Citation: Allen-King, R. M., D. P. Divine, M. J. L. Robin, J. R. Alldredge, and D. R. Gaylord (2006), Spatial distributions of perchloroethylene reactive transport parameters in the Borden Aquifer, Water Resour. Res., 42, W01413, doi:10.1029/2005WR003977.

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