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AGU: Geophysical Research Letters

 

Keywords

  • organic carbon
  • light absorption
  • radiative transfer

Index Terms

  • Atmospheric Composition and Structure: Aerosols and particles
  • Atmospheric Composition and Structure: Pollution: urban and regional
  • Atmospheric Composition and Structure: Troposphere: composition and chemistry

Abstract

GEOPHYSICAL RESEARCH LETTERS, VOL. 34, L17813, 5 PP., 2007
doi:10.1029/2007GL029797

Color of brown carbon: A model for ultraviolet and visible light absorption by organic carbon aerosol

Haolin Sun

Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA

Laura Biedermann

Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA

Tami C. Bond

Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA

We recommend ultraviolet and visible absorption spectra to represent particular types of atmospheric organic particles. Spectra of liquids and particles can be compared using the absorption coefficient of bulk material divided by material density. Reported absorption by absorbing organic aerosol from combustion is greater than that of organic material isolated by humic acid extraction. We examine ultraviolet and visible spectra of 200 organic compounds, concluding that visible absorption may be attributable to n → π* electronic transitions in a small fraction of oxygenated compounds. Absorption spectra can be communicated using the band-gap and Urbach relationships instead of the absorption Angstrom exponent. Water-soluble atmospheric aerosol has a band-gap of about 2.5 eV; insoluble aerosol may have a lower band-gap and higher absorption. Although different types of organic carbon may exhibit a continuum in absorption, there is a sharp distinction between the most-absorbing organic carbon and black carbon.

Received 1 March 2007; accepted 3 August 2007; published 12 September 2007.

Citation: Sun, H., L. Biedermann, and T. C. Bond (2007), Color of brown carbon: A model for ultraviolet and visible light absorption by organic carbon aerosol, Geophys. Res. Lett., 34, L17813, doi:10.1029/2007GL029797.

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