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AGU: Journal of Geophysical Research, Atmospheres

 

Keywords

  • charged fraction
  • diameter growth rates
  • new particle formation

Index Terms

  • Atmospheric Composition and Structure: Aerosols and particles
  • Atmospheric Processes: Atmospheric electricity
  • Atmospheric Composition and Structure: Ion chemistry of the atmosphere
Abstract
Cited By (2)
 

Abstract

Estimating nanoparticle growth rates from size-dependent charged fractions: Analysis of new particle formation events in Mexico City

Kenjiro Iida

Particle Technology Laboratory, University of Minnesota, Minneapolis, Minnesota, USA

Mark R. Stolzenburg

Particle Technology Laboratory, University of Minnesota, Minneapolis, Minnesota, USA

Peter H. McMurry

Particle Technology Laboratory, University of Minnesota, Minneapolis, Minnesota, USA

James N. Smith

Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, Colorado, USA

A method to estimate nanoparticle diameter growth rates (GR) during new particle formation (NPF) events from the measured dependence of charged fraction, f, on size, D p , is introduced. The method is especially useful for observations during intense particle production rates, when the mode in the distribution of newly formed particles does not grow monotonically with time. This method assumes that the observed profile of f versus D p during the nucleation and growth period is controlled by condensational growth, ion-particle combination/recombination, scavenging by preexisting particles, and coagulation among growing nanoparticles. Values of growth rates obtained by this method (GR f ) agree well with independently obtained particle growth rates due to gas-to-particle conversion processes (GR PSD ) during regional NPF events. The method was then applied to characterize the NPF events observed at Tecamac, Mexico. These growth rates were found to range from 15–40 nm/h, which is significantly higher than values reported for other urban areas. The production rates for 1 nm particles calculated from the estimated growth rates and measured Fuchs surface area (J 1nm = 1900–3000 particles/cm3 s) are comparable to those recently observed in New Delhi. Because critical nuclei are likely close to 1 nm in size, J 1nm should provide a reasonable estimate for nucleation rates.

Received 7 August 2007; accepted 11 December 2007; published 5 March 2008.

Citation: Iida, K., M. R. Stolzenburg, P. H. McMurry, and J. N. Smith (2008), Estimating nanoparticle growth rates from size-dependent charged fractions: Analysis of new particle formation events in Mexico City, J. Geophys. Res., 113, D05207, doi:10.1029/2007JD009260.

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