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AGU: Paleoceanography

 

Keywords

  • carbon
  • isotope
  • kerogen
  • Okinawa Trough

Index Terms

  • Biogeosciences: Carbon cycling
  • Geochemistry: Stable isotope geochemistry
  • Biogeosciences: Biogeochemical cycles, processes, and modeling
  • Paleoceanography: Biogeochemical cycles, processes, and modeling
  • Geochemistry: Organic and biogenic geochemistry
Abstract
Cited By (1)
 

Abstract

Enhanced supply of fossil organic carbon to the Okinawa Trough since the last deglaciation

S. J. Kao

Research Center for Environmental Changes, Academia Sinica, Taipei, Taiwan

M. H. Dai

State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, China

K. Y. Wei

Department of Geosciences, National Taiwan University, Taipei, Taiwan

N. E. Blair

Departments of Civil and Environmental Engineering and Earth and Planetary Sciences, Northwestern University, Evanston, Illinois, USA

W. B. Lyons

Byrd Polar Research Center, Ohio State University, Columbus, Ohio, USA

Significantly older 14C ages by 2500–7900 years are found for sedimentary total organic carbon (TOC) when compared to ages of codeposited surface-dwelling foraminifera in the southern Okinawa Trough. This age discrepancy increases with rising sea level since the Last Glacial Maximum. A progressive shift in TOC δ 13C toward more negative values with rising sea level reflects an increasing fractional contribution of terrestrial organics (soil organics, plant debris, and/or fossil organics) to the buried organic pool. Organic matter previously stored on the East China Sea shelf during sea level lowstand and riverine material from Taiwan may be the sources that cause the δ 13CTOC to shift to more terrestrial values. During the Holocene when sea level is above −40 m, δ 13CTOC values stabilize within a narrow range (−22.3 to −22.8‰) while age discrepancies continue to increase and less chemically weathered sediments are deposited. The increase in age discrepancy between TOC and foraminifera in the Holocene may be due to a wetter climate that drove higher rates of physical weathering on Taiwan and greater transport rates of fossil organic C-bearing lithogenic sediment to the ocean. The climate impact on the relative delivery of fossil and nonfossil TOC in depositional settings influenced by fluvial sources should be considered in interpretations of sedimentary C isotope records.

Received 23 February 2007; accepted 7 February 2008; published 7 May 2008.

Citation: Kao, S. J., M. H. Dai, K. Y. Wei, N. E. Blair, and W. B. Lyons (2008), Enhanced supply of fossil organic carbon to the Okinawa Trough since the last deglaciation, Paleoceanography, 23, PA2207, doi:10.1029/2007PA001440.

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