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AGU: Water Resources Research

 

Keywords

  • colloids
  • sand
  • contact angle
  • attachment
  • facilitated transport

Index Terms

  • Hydrology: Vadose zone
  • Hydrology: Soils
  • Hydrology: Groundwater quality
  • Hydrology: Groundwater transport

Abstract

WATER RESOURCES RESEARCH, VOL. 45, W12403, 10 PP., 2009
doi:10.1029/2008WR007322

Transport and retention of colloidal particles in partially saturated porous media: Effect of ionic strength

Yuniati Zevi

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

Annette Dathe

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

Bin Gao

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

Wei Zhang

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

Brian K. Richards

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

Tammo S. Steenhuis

Department of Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA

We directly observed pore-scale attachment of fluorescent synthetic polystyrene colloids (1.0 μm diameter) in a partially saturated sand pack (pore space saturation ranging from 0.7 to 0.9) at four solution ionic strengths (0, 1, 100, 200 mmol NaCl). Sequential confocal laser microscope images were analyzed to quantify colloid retention, particularly at air-water meniscus-solid (AWmS) interfaces. We concurrently measured effluent colloid concentrations to determine overall matrix retention. Ionic strength had no effect on meniscus contact angles (26.7 ± 3.7 degrees) or surface tension (63–67 mN/m), both important components of the capillary forces thought to play the primary role in retention at the AWmS interfaces. AWmS interfaces attachment was greatest at 1 mmol, with the 0 mmol ionic strength reducing attachment by half. Increasing ionic strength to 100 and 200 mmol markedly decreased colloid retention at the AWmS interfaces due to observed increased competing attachment at grain surfaces (solid/water interface) that reduced the number of colloids available for AWmS interface attachment.

Received 30 July 2008; accepted 28 August 2009; published 4 December 2009.

Citation: Zevi, Y., A. Dathe, B. Gao, W. Zhang, B. K. Richards, and T. S. Steenhuis (2009), Transport and retention of colloidal particles in partially saturated porous media: Effect of ionic strength, Water Resour. Res., 45, W12403, doi:10.1029/2008WR007322.

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