Abstract
WATER RESOURCES RESEARCH,
VOL. 45,
W08412,
11 PP., 2009
doi:10.1029/2008WR007459
Characterization of unsaturated porous media by high-field and low-field NMR relaxometry
Agrosphere Institute, Forschungszentrum Jülich, Jülich, Germany
Agrosphere Institute, Forschungszentrum Jülich, Jülich, Germany
Phytosphere Institute, Forschungszentrum Jülich, Jülich, Germany
Agrosphere Institute, Forschungszentrum Jülich, Jülich, Germany
Phytosphere Institute, Forschungszentrum Jülich, Jülich, Germany
Department of Technical Physics II, University of Technology, Ilmenau, Germany
Agrosphere Institute, Forschungszentrum Jülich, Jülich, Germany
A comparison study of nuclear magnetic resonance relaxometry at high and low magnetic field (7 and 0.1 T) has been initiated
for investigating the influence of the magnetic field strength, variable clay content, and different degrees of saturation
on the relaxometric properties of four ideal porous media. The samples consisted of medium sand with increasing fractions
of kaolin clay ranging from 0 to 15%. Six different volumetric water contents between saturation and
= 0.05 were used. Changes in water content of the samples were achieved by slow evaporation. T 2 relaxation curves were monitored by the Carr-Purcell-Meiboom-Gill sequence and were further analyzed by inverse Laplace transformation,
yielding T 2 distribution functions. Sand shows a slight continuous shift with decreasing water content of a bimodal distribution function
of T 2 to faster relaxation at high and low magnetic field. Sand-clay mixtures show broad, bimodal distribution functions for both
magnetic field intensities which shift slightly with decreasing water content. Signal amplitude behavior with variation of
saturation degree was also monitored. An expected proportionality of the total signal amplitude with water content was observed
for all samples at 0.1 T, whereas at 7 T deviations occurred for samples with a clay content higher than 5%, which are assigned
to loss of signal in the first echo periods. The relaxivity in unsaturated clay-based porous media is mostly surface dominated,
as the weak and comparable dependence of 1/T 2 on T E at both field strengths shows. Nevertheless, for a reliable determination of water content in mixed systems with varying
texture and saturation the employment of multiecho sequences at low magnetic field strength are preferable.
Received 16 September 2008; accepted 29 May 2009; published 11 August 2009.
Citation: (2009), Characterization of unsaturated porous media by high-field and low-field NMR relaxometry, Water Resour. Res., 45, W08412, doi:10.1029/2008WR007459.
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