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G-Cubed: Geochemistry, Geophysics, Geosystems

 

Keywords

  • gas hydrate
  • hydrate-bearing sediment
  • phase transformation
  • strain

Index Terms

  • Marine Geology and Geophysics: Gas and hydrate systems
  • Marine Geology and Geophysics: Marine sediments: processes and transport
  • Hydrology: Frozen ground
  • Physical Properties of Rocks: Microstructure
Abstract
Cited By (6)
 

Abstract

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS, VOL. 11, Q03007, 13 PP., 2010
doi:10.1029/2009GC002667 [Citation]

Volume change associated with formation and dissociation of hydrate in sediment

J. Y. Lee

Petroleum and Marine Resources Division, Korea Institute of Geoscience and Mineral Resources, 92 Gwahang-no, Yuseong-gu, Daejeon 305-350, South Korea

J. Carlos Santamarina

School of Civil and Environmental Engineering, Georgia Institute of Technology, 790 Atlantic Drive, Atlanta, Georgia 30332-0355, USA

C. Ruppel

U.S. Geological Survey, 384 Woods Hole Road, Woods Hole, Massachusetts 02543, USA

Gas hydrate formation and dissociation in sediments are accompanied by changes in the bulk volume of the sediment and can lead to changes in sediment properties, loss of integrity for boreholes, and possibly regional subsidence of the ground surface over areas where methane might be produced from gas hydrate in the future. Experiments on sand, silts, and clay subject to different effective stress and containing different saturations of hydrate formed from dissolved phase tetrahydrofuran are used to systematically investigate the impact of gas hydrate formation and dissociation on bulk sediment volume. Volume changes in low specific surface sediments (i.e., having a rigid sediment skeleton like sand) are much lower than those measured in high specific surface sediments (e.g., clay). Early hydrate formation is accompanied by contraction for all soils and most stress states in part because growing gas hydrate crystals buckle skeletal force chains. Dilation can occur at high hydrate saturations. Hydrate dissociation under drained, zero lateral strain conditions is always associated with some contraction, regardless of soil type, effective stress level, or hydrate saturation. Changes in void ratio during formation-dissociation decrease at high effective stress levels. The volumetric strain during dissociation under zero lateral strain scales with hydrate saturation and sediment compressibility. The volumetric strain during dissociation under high shear is a function of the initial volume average void ratio and the stress-dependent critical state void ratio of the sediment. Other contributions to volume reduction upon hydrate dissociation are related to segregated hydrate in lenses and nodules. For natural gas hydrates, some conditions (e.g., gas production driven by depressurization) might contribute to additional volume reduction by increasing the effective stress.

Received 8 June 2009; accepted 17 December 2009; published 11 March 2010.

Citation: Lee, J. Y., J. C. Santamarina, and C. Ruppel (2010), Volume change associated with formation and dissociation of hydrate in sediment, Geochem. Geophys. Geosyst., 11, Q03007, doi:10.1029/2009GC002667.

Cited By

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