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2.1.1. Tritium.

Tritium is the heavy isotope of hydrogen; it undergoes radioactive decay into He with a half- life of 12.43 years [ Taylor and Roether, 1982]. Analysis for tritium is done in the laboratory via gas proportional counting [cf. Östlund and Dorsey, 1977] and mass spectrometric measurement [cf. Clarke et al., 1976]; the latter method is also used for He [cf. Lott and Jenkins, 1984]. Tritium is delivered to the oceans via vapor exchange, rain, and continental runoff. It is most commonly found in the oceans in the form HTO (proton-tritium-oxygen) [ Östlund and Mason, 1977]. Pre- bomb naturally occurring background levels of tritium are estimated to be about 0.2 to 0.5 TU in surface waters [ Begemann and Libby, 1957; Dreisigacker and Roether, 1978], where 1 TU = 10*[T/H]. The bomb tests of the 1950s and particularly the early 1960s increased the atmospheric tritium inventories by at least two orders of magnitude [ Craig and Lal, 1961; Eriksson, 1965]. Most of the bomb tritium entered the surface waters of the high northern latitude oceans within a few years causing a tritium maximum in surface waters in about 1964. Several studies have used models to simulate the tritium delivery to the North Atlantic Ocean as a function of time [e.g. Dreisigacker and Roether, 1978; Weiss et al., 1979; Weiss and Roether, 1980; Koster et al., 1989]. Recently Doney et al. [1993] formulated a model for the period 1950-86 that agrees to within 10% with the water column inventories. The model results show that starting in the mid-1970s, the annual tritium input from the Arctic exceeded that of all the other sources combined (Figure 2a).



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Rev. Geophys. Vol. 33 Suppl., © 1995 American Geophysical Union