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2.2. Tracer Time Scales

The concept of ``age'' is used to mean the elapsed time since a water mass was last at the ocean surface in direct contact with the atmosphere. When in contact with the atmosphere the water is ventilated, that is it gets renewed with respect to atmospheric gas concentrations. If the age and distance from the region of ventilation are known, and a pathway is assumed, then the velocity can be calculated. The age information can be derived from radioactive decay as for tritium, or from the temporally changing atmospheric concentrations as for the CFCs.

Measurement of tritium and its daughter product He on the same sample can be used to calculate an age [e.g. Jenkins and Clarke, 1976]. The tritium/He age in years (ç) is calculated according to:

where [H] and [He] are the concentrations of tritium and He in tritium units. The He concentration is reset to near zero in the surface waters, although He concentrations above solubility equilibrium have been observed in regions of ice cover or upwelling [e.g. Fuchs et al., 1987; Schlosser et al., 1990]. The He in the oceans is derived from two sources: radiogenic from decay of tritium, and primordial from ridge systems. The concentrations of He in the deep waters of the North Atlantic are considerably lower than those in the Pacific [ Jenkins and Clarke, 1976]. Recently Doney and Jenkins [1994] have had success correcting for the primordial He signal using correlations with silica concentrations. In the western North Atlantic, they found the primordial effect on the tritium/He derived velocity of the DWBC is small. An advantage of using the tritium/He age is that it is independent of the initial tritium concentration of a water mass [ Schlosser and Smethie, 1995].

The CFC age is calculated using an atmospheric mixing ratio (þ*) [cf. Weiss et al., 1985; Wallace and Moore, 1985; Fine et al., 1988] as follows:

where C, and C are measured seawater concentrations of two CFC compounds, F and Fare their solubility functions, is the potential temperature, and S is the salinity. The calculated atmospheric mixing ratio can then be compared with past atmospheric ratios (e.g., Figure 2) to determine a date of equilibration or age. The age will be a true age if: the water mass was in equilibrium with the atmosphere at the time of formation, mixing occurs only with CFC-free water, and the CFC concentration ratio is unaltered during the process of formation and flow over the sills.

Tritium/He ages can be applied to oceanographic processes occurring on time scales of several months up to several decades. The tritium/He age is limited by the measurement precision of He/He and tritium concentrations [ Schlosser and Smethie, 1995]. The CFC ages are mostly limited to those years when the atmospheric ratio of two compounds has been increasing at different rates. The F11/F12 ratio can be applied to processes that occurred during the period of the 1950s to the mid-1970s, the F113/F11 ratio for the mid-1970s to the present, and the CCl/F11 ratio for the 1950s (limited by F11) to the present. Thus, as these transient tracers are transported equatorward in the DWBC, they serve as a marker for waters formed in the high latitudes, and they carry a built in time clock.



next up previous
Next: 2.3. North Atlantic Up: 2. Review Previous: 2.1.2. Chlorofluorocarbons.



U.S. National Report to IUGG, 1991-1994
Rev. Geophys. Vol. 33 Suppl., © 1995 American Geophysical Union