In plasticity, correlation between density and strength is not very obvious, rather the crystal structure plays an important role (Frost and Ashby, 1982; Karato, 1989). Notable examples are the B1-B2 (fcc to bcc) transition in NaCl (Meade and Jeanloz, 1988b), the transition of pyroxene to garnet (Karato et al., 1994), and the structural phase transformations in perovskites (Fujino et al., 1993). The low temperature yield strength of a B2 phase (the CsCl structure) is much smaller than that of a B1 phase (the NaCl structure), which can be explained by the classical Peierls theory, in which the yield strength of a crystalline material is related to crystal structure (Takeuchi and Suzuki, 1988). The effect of crystal structure on high temperature creep is more difficult to interpret because of the complex nature of the controlling mechanisms (see e.g., Frost and Ashby, 1982). However, crystal structure appears to play an important role in controlling the resistance to dislocation glide (Karato, 1989).
The strengths of the
-phase (a high pressure polymorph
of olivine) and garnet remain controversial subjects. Bussod
et al. (1993) estimated that
-phase is significantly
stronger than olivine. In contrast, Young et al. (1992)
inferred it to be significantly weaker than olivine. Tingle
et al. (1991) measured the high temperature creep strength of
a spinel phase (
-phase) of Mg
GeO
and
found a slightly higher strength than olivine phase. Based on
the studies on analogue materials, Karato et al. (1994)
emphasized a high strength of garnets in general, whereas
Doukhan et al. (1994) emphasize the ductility of high
pressure garnets based on TEM (transmission electron
microscopy) observations of dislocation structures in
naturally deformed specimens. In contrast, based on the TEM
observations, Ingrin and Madon (1994) found evidence for
higher strength of garnet than co-existing spinel being
consistent with Karato et al. (1994).
The only available data on the strength of perovskite are
either room temperature measurements of the yield strength of
MgSiO
perovskite (Meade and Jeanloz, 1990; Karato et
al., 1990) and the results on analogue materials. The
applicability of the analogue materials approach in
plasticity of perovskite has been controversial. Poirier and
his group found a large diversity of plastic behavior of
perovskites and emphasized the limitation of the use of the
analogue materials (Poirier et al., 1989; Beauchesne and
Poirier, 1990; Wright et al., 1992). In contrast, Wang et al.
(1993) argued that the analogue materials approach will be
useful for the hard slip system that presumably controls the
strength of an aggregate. Karato and Li (1992) found an
importance of diffusion creep in CaTiO
perovskite and
predicted that the lower mantle will be seismological
isotropic if diffusion creep is important in the lower
mantle.