next up previous
Next: Advances in Mathematical Up: Research on Processes Previous: Biodegradation Rates

Temperature

Subsurface temperature is an important environmental variable in SVE remediation processes. The efficiency of SVE remediation is strongly linked to the vapor pressures of the target compounds with a suggested lower limit on vapor pressure of 1000 Pa [ Peterson et al. , 1988; Johnson et al. , 1990a]. Vapor pressures of organic compounds increase by a factor of approximately 3 or 4 with every 10 C rise in temperature. Experimental evidence also suggests that vapor sorption is inversely proportional to temperature [ Goss, 1992].

The effect of subsurface temperature on the design and operation of BV remediation efforts has received little attention. It is generally accepted that soil temperatures at most sites are within the limits for microbial growth [ Litchfield, 1993]. In Alaska, where soil temperatures are as low as 1 C, respiration rates comparable to those in temperate and subtropical regions were observed during summer months [ Ong et al. , 1994; Kellems et al. , 1994]. The observed rates dropped slightly during the winter months with less effect noted at sites with either active or passive soil warming.

Methods to increase SVE efficiency by increasing the subsurface temperature have been attempted. At a diesel contaminated site, ambient air was heated to 177 C before injection [ Sittler et al. , 1993]. Increases in subsurface air temperatures of up to 28 C were observed as far as 9m from the nearest injection well. Steam injection for removal of NAPLs in the saturated zone has also been studied [ Hunt et al. , 1988; Falta et al. , 1992; Wilson and Clarke, 1992; Adenekan and Patzek, 1993]. Other novel approaches integrating SVE with methods for soil heating are described by Downey and Elliott [1990].



U.S. National Report to IUGG, 1991-1994
Rev. Geophys. Vol. 33 Suppl., © 1995 American Geophysical Union